Faculty manager Paul Hudson said: "It has been another good year for students taking AS and A Levels at Pembrokeshire College.
"There have been some outstanding individual achievements with a good overall pass rate. The mature students have also done very well."
Many of the students have opted to carry on with their studies at university or college.
Learning services manager Maxine Thomas commented that: "So far all our students have been offered their first choice of their chosen university with many being accepted by the top-of-the-league table universities.
"What is interesting this year is the range of topics being studied, including medicine, journalism, physiotherapy, French, drama, forensic science and physics."
Among the individuals who did exceptionally well completing their A Levels were Jo-Dee Williams, of Milford Haven; Natasha Embleton, of Kilgetty; Anna Morrison and Lucy Hollis, of Carmarthen; Sian Jones, of Narberth; Cui Wang, of China; and Lucy Griffiths, of Haverfordwest.
Jo-dee Williams is going to study physiotherapy at Cardiff after achieving four straight A Levels in biology, chemistry, psychology and geography.
Jo-Dee said: I'm really ecstatic! My time here at Pembrokeshire College has gone really quickly. I've made lots of friends from many different schools and the lecturers have been very good."
Students taking AS Levels who also did exceptionally well were Molly Brown, of Pantry Fields, Newport; Matthew Giles, of Llanycefn; and Adam Cuerden, of Haverfordwest, who also took his maths A Level in one year.
Molly Brown, who got four A grades and is hoping to take English or history at Warwick, Durham or Bristol after completing her A Levels at Pembrokeshire, said: "I'm amazed - I got B grades in my mocks. I love the college, I knew it was going to be very good here socially and that I would get a lot of support in my studies, but my results have also proved how academically good it is here as well."